enzymatic redox reaction of molybdenum

  • Molybdenum CofactorContaining Enzymes: Structure and ...

    Molybdenum containing enzymes catalyze basic metabolic reactions in the nitrogen, sulfur, ... into water, to or from a substrate in a two electron redox reaction.

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  • Electrochemical evidence that pyranopterin redox chemistry ... PNAS

    Nov 11, 2015 ... We prove that YedY, a structurally simple mononuclear Mo enzyme, ... reactions has been attributed to the Mo(IV)/Mo(V)/Mo(VI) oxidation state...

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    Oxotransferases Holm Research Group Harvard University

    Mo and W containing enzymes are relatively common in Nature, being present in a ... These enzymes catalyze a variety of redox reactions, including, primarily,...

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    Redox chemistry of molybdenum in natural waters and its ...

    Dec 21, 2012 ... The existences of diverse Mo redox species probably facilitated the emergences of Mo enzymes (or prototypes) catalyzing metabolic reactions...

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    Molybdenum enzymes an overview ScienceDirect Topics

    Members of the first two families catalyse redox reactions. ... As in the xanthine oxidase family of Mo enzymes, there appear to be no ligands contributed by the...

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    Chemical keys to molybdenum enzymes RSC Publishing

    of methane and in the oxidation of formate, carbon monoxide, and various aldehydes, the molybdenum enzymes again have a prominent position. Clearly, the...

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    Mechanistic aspects of molybdenum containing enzymes

    well over 50 such enzymes have been identi¢ed that catalyze a variety of hydroxylation, oxygen atom transfer and other oxidation reduction reactions. Many of...

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    (PDF) Molybdenum cofactor containing enzymes: Structure and ...

    PDF Molybdenum containing enzymes catalyze basic metabolic reactions in the nitrogen, ... by the reduction of Mo(VI) and the oxidation of Mo(IV), respectively.

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    Mechanistic aspects of molybdenum containing enzymes FEMS ...

    As discussed above, in most prokaryotic enzymes the ... 'Umpolung' of the substrate could occur by oxidation...

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